期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 3, 页码 1145-1155出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo402577n
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资金
- National Science Foundation [CHE-0847262]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0847262] Funding Source: National Science Foundation
An operationally simple, inexpensive, and rapid route for the olefination of a wide array of trifluoromethyl ketones to yield 3,3,3-trifluoromethylpropenes is reported. Using a Peterson olefination approach, the reaction gives good to excellent yields of the alkene products and can be performed without purification of the beta-hydroxysilyl intermediate. The reaction can be extended to other perfluoroalkyl substituents and is easily scaled up. The alkenes prepared can be readily transformed into a variety of other perfluoroalkyl-containing compounds.
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