期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 3, 页码 1454-1460出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo402366p
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资金
- Natural Science Foundation of China [21302099]
- Natural Science Foundation of Jiangsu Province [BK2012449]
- Natural Science Foundation of Jiangsu Provincial Colleges and Universities [12KJB150014]
- Scientific Research Start-up Foundation of Nanjing Normal University [2011103XGQ0250]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
Highly selective carbonylative Suzuki reactions of aryl iodides with arylboronic acids using an in situ generated nanopalladium system furnished products in high yields. The reactions were performed under ambient conditions and in the absence of an added ligand. The key to success is the addition of pivalic acid, which can effectively suppress undesired Suzuki coupling. The synthesis can be easily scaled up, and the catalytic system can be reused up to nine times. The nature of the active catalytic species are discussed.
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