期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 14, 页码 6395-6402出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo5005845
关键词
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资金
- National Natural Science Foundation of China [21272070, 21072057]
- National Basic Research Program of China (973 Program) [2010CB126101]
- Twelfth Five-year Plan of China [2011BAE06B01-15]
A mild and versatile method for the construction of C-N bonds by the reaction of (2,2-difluorovinyl)arenes with various N-H-containing heterocycles in the presence of K3PO4 has been developed. The reaction proceeded efficiently at room temperature (25 degrees C) affording the (E)-N-alpha-fluorovinyl derivatives of azoles 3 in good to excellent yields with relatively high stereoselectivity.
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