期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 7, 页码 3206-3214出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo402798k
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资金
- National Science Council of Taiwan [NSC 99-2628-B-037-003-MY3]
- Department of Health Executive Yuan, Taiwan [DOH101-TD-C-111-004]
A diverse library of novel carbamates was synthesized utilizing copper-catalyzed oxidative C-O coupling of formamides and salicylaldehydes. Sensitive aldehyde groups remained intact in the presence of an oxidant and a transition-metal salt. Salicylaldehydes bearing electron-donating, electron-withdrawing, and halogen groups as well as 1-hydroxy-2-naphthaldehydes provided the desired carbamates in good to excellent yields.
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