期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 21, 页码 10189-10195出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo5018537
关键词
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资金
- National Natural Science Foundation of China [21172080, 21372089]
- Changjiang Scholars and Innovation Team Project of Ministry of Education
The NaBH4 (or TBABH(4))-promoted electrochemically reductive cleavage of aryl CO bonds in diaryl ethers to produce phenols and arenes with high yields and excellent selectivities at room temperature was reported. Air- and water-tolerable, this process also works on the cleavage of aryl alkyl and benzyl ethers. The application to break the beta-O-4, alpha-O-4, and 4-O-5 lignin model compounds is also illustrated, which highlights the advance toward the goal of lignin conversion.
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