期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 19, 页码 9408-9412出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo5017585
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资金
- University of Minnesota, Morris (UMM)
- University of Minnesota Office of the Vice President for Research
- UMM Division of Science and Mathematics
- Office of the Dean of the Graduate School and the Supercomputing Institute of the University of Minnesota
- National Science Foundation Major Research Instrumentation Award [1125975]
- CSUN New Faculty Start-up Fund
Benzo[1,2-b:4,5-b']dithiophenes were oxidized under mild conditions with m-CPBA to yield the corresponding bis-sulfones (or tetraoxides). These sulfones possess red-shifted absorption and emission spectra relative to the parent molecules. Electrochemical analyses reveal that the benzodithiophene molecules are transformed from electron donors to electron acceptors.
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