期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 20, 页码 9639-9646出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501769t
关键词
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资金
- Agence Nationale de la Recherche (ANR) within the ANR Blanc Chiracid project
- Estonian Ministry of Education and Research [IUT14-20 (TLOKT14014I)]
Phosphoric acids with planar chiral paracyclophane scaffolds have been prepared in optically pure form starting from 1,8-dibromobiphenylene, by means of a chiral phosphorodiamidate as the phosphorylating agent Structural characterization and configurational assignment have been performed by X-ray diffraction studies. The acids promote the organocatalytic enantioselective H-transfer reduction of alpha-arylquinolines with up to 90% enantiomeric excess.
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