期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 20, 页码 9655-9668出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501793q
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资金
- IISc CSIR, New Delhi [01(2415)/10/EMR-II]
- RL Fine Chem
- CSIR
A facile transition-metal-free oxidative cross-dehydrogenative coupling reaction involving selective formation of a C-S bond leading to the synthesis of arylthiobenzoxazoles, heteroarylthiobenzoxazoles, and arylthiobenzothiazoles has been described. This highly regioselective C-H functionalization reaction with electron-rich aromatic systems including heteroaromatics is achieved by reversing the reactivity of sulfur in the presence of a suitable oxidant and strong acid.
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