期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 7, 页码 2916-2925出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo402810s
关键词
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资金
- INSA Rouen
- Rouen University
- CNRS
- EFRD
- Labex SynOrg [ANR-11-LABX-0029]
- Region Haute-Normandie (CRUNCh network)
- EFRD [EFRD 32819, EFRD 43209]
We report herein the first general access to fluorinated homoallylic amines by means of an addition of fluorinated organoindium reagent. The corresponding amines were obtained in good to excellent yield with excellent diastereoisomeric ratio. A plausible mechanism is proposed to explain the stereochemical outcome of the reaction based on the X-ray structure of the products.
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