4.7 Article

Mechanistic Insight into Transition Metal-Catalyzed Reaction of Enynal/Enynone with Alkenes: Metal-Dependent Reaction Pathway

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JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 13, 页码 6113-6122

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AMER CHEMICAL SOC
DOI: 10.1021/jo500838x

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  1. Program for New Century Excellent Talents in University [NCET-10-0403]
  2. National Basic Research Program of China (973) [2011CB808600]

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A systematic study of the transition metal-catalyzed reaction of enynal/enynone with alkenes has been reported. It was found that the reaction has two metal-dependent reaction pathways. One led to the formation of 1,2-DHN, while another led to cyclic-o-QDM.

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