期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 5, 页码 2226-2241出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo5000829
关键词
-
资金
- National Institutes of Health [R01 GM086483]
- National Science Foundation
A second-generation synthesis of three structurally related chlorosulfolipids has been developed. Key advances include highly stereocontrolled additions to alpha,beta-dichloroaldehydes, kinetic resolutions of complex chlorinated vinyl epoxide intermediates, and Z-selective alkene cross metatheses of cis-vinyl epoxides. This strategy facilitated the synthesis of enantioenriched danicalipin A, mytilipin A, and malhamensilipin A in nine, eight, and 11 steps, respectively.
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