期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 18, 页码 8577-8583出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501143m
关键词
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资金
- Natural Science Foundation of China [21172162, 21372174]
- Ph.D. Programs Foundation of Ministry of Education of China [2013201130004]
- Young National Natural Science Foundation of China [21202111]
- Young Natural Science Foundation of Jiangsu Province [BK2012174]
- Key Laboratory of Organic Synthesis of Jiangsu Province [KJS1211]
- PAPD
- Soochow University
Chemoselective 2-isocyanoethylindole-based domino reactions for the construction of polycyclic spiroindoline derivatives and polysubstituted pyrroles have been developed. The reaction of 2-isocyanoethylindoles and gem-diactivated olefins lead to the polycyclic spiroindoline derivatives (up to 92% yields) in EtOH under reflux conditions. Furthermore, the three-component reaction of 2-isocyanoethylindoles with gem-diactivated olefins and secondary amines afford polysubstituted pyrroles (in moderate yields) in CH3CN under reflux conditions.
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