期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 3, 页码 1084-1092出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo402540j
关键词
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资金
- Natural Science Foundation of China [21176223]
- National Natural Science Foundation of Zhejiang [LY13B020016]
- Key Innovation Team of Science and Technology in Zhejiang Province [2010R50018]
We report a novel molecular iodine-catalyzed 1,3-dipolar cycloaddition/oxidation/aromatization cascade process with hydrogen peroxide as the terminal oxidant for the construction of pyrrolo[2,1-a]isoquinolines. The product pyrrolo[2,1-a]isoquinolines were obtained from reactions between simple, readily available dipolarophiles and tetrahydroisoquinolines in moderate to excellent yields without the need for a metal catalyst.
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