期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 24, 页码 11933-11939出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501691f
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资金
- Monbusho (The Ministry of Education, Culture, Sports, Science and Technology)
- JST Strategic Basic Research Programs Advanced Catalytic Transformation Program for Carbon Utilization (ACT-C) from Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [22105002, 14J03693] Funding Source: KAKEN
The Ni(II)-catalyzed direct arylation of C(sp(3))-H (methyl and methylene) bonds in aliphatic amides containing an 8-aminoquinoline moiety as the directing group with diaryliodonium salts as coupling electrophiles is described. A wide variety of functional groups are tolerated in the reaction. The reaction represents the first example of the Ni-catalyzed direct arylation of C(sp(3))-H bonds with diaryliodonium salts.
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