期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 11, 页码 5374-5378出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo500842e
关键词
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资金
- National Natural Science Foundation of China [21172106, 21372114, 21272178]
- National Basic Research Program of China [2010CB923303]
- Research Fund for the Doctoral Program of Higher Education of China [20120091110010]
A sequential oxidative radical alkoxycarbonylation and aromatization of 2-isocyanobiphenyl with carbazates was developed to furnish phenanthridine-6-carboxylates. Various functional groups such as methoxy, chloro, fluoro, trifluoromethoxy, and trifluoromethyl groups were tolerated well under the reaction conditions. The sequential radical addition-cyclization strategy represents a practical route to access phenanthridine-6-carboxylates.
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