期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 11, 页码 5028-5035出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo500586a
关键词
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资金
- Japan Society for the Promotion of Science
- [1381002900]
- Grants-in-Aid for Scientific Research [13J10638, 26620149] Funding Source: KAKEN
In sharp contrast to many examples of transition-metal-catalyzed hydrothiolation of alkynes, the corresponding catalytic addition of thiols to alkenes has remained undeveloped. However, a novel Pd-catalyzed addition of thiols to alkenes bearing a heteroatom, such as oxygen and nitrogen, is found to proceed under mild conditions to give the corresponding Markovnikov adducts, regioselectively, in good yields.
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