期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 8, 页码 3678-3683出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo500312n
关键词
-
资金
- Chinese National Natural Science Foundation [21202135]
- Natural Science Foundation of Fujian Province of China [2013J05031, 2012J01053]
- National Basic Research Program of China [2012CB821600]
A novel and efficient Cs2CO3-promoted phosphorylation or phosphinylation of various 1,1-dibromo-1-alkenes with readily available trialkyl phosphites, ethyl diphenylphosphinite, or diethyl phenylphosphonite has been developed under metal-free conditions, providing a practical and powerful tool for one-pot synthesis of valuable alkynylphosphonates, -phosphinates, and -phosphine oxides in good to excellent yields.
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