期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 9, 页码 4366-4372出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo400342y
关键词
-
资金
- JSPS KAKEHNHI [21590003]
- Grants-in-Aid for Scientific Research [25460004] Funding Source: KAKEN
Anti carbocyanative cyclization using 1,6-enynes under nickel catalysis is described. This reaction is triggered by hydronickelation to alkenes followed by carbometalation. Steric repulsion caused by the bulky substituents on alkynes promotes isomerization of the carbon-carbon double geometry in an organonickel intermediate to introduce both alkyl and cyano groups in an anti fashion.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据