4.7 Article

Rhodium-Catalyzed Decarboxylative and Dehydrogenative Coupling of Maleic Acids with Alkynes and Alkenes

期刊

JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 22, 页码 11427-11432

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jo401992d

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资金

  1. MEXT
  2. JSPS
  3. JST, Japan
  4. Grants-in-Aid for Scientific Research [25288048, 25105733] Funding Source: KAKEN

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The dehydrogenative coupling of maleic acids with alkynes proceeds smoothly accompanied by decarboxylation under rhodium catalysis to produce variously substituted a-pyrone derivatives. The catalyst system is also applicable to the coupling with 1,3-diynes and alkenes.

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