期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 18, 页码 9377-9382出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo401585v
关键词
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资金
- National Natural Science Foundation of China [20772030, 21072056, 21272067]
- Fundamental Research Funds for the Central Universities
- Scientific Research Foundation for the Returned Overseas Chinese Scholars
- State Education Ministry
An efficient enantioselective hydrazination/cyclization cascade reaction of alpha-substituted isocyanoacetates to azodicarboxylates catalyzed by Cinchona alkaloid derived squaramide catalysts has been investigated, affording the optically active 1,2,4-triazolines in excellent yields (up to 99%) and good to excellent enantioselectivities (up to 97% ee) under mild conditions.
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