期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 10, 页码 5022-5025出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo302791q
关键词
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资金
- National Science Foundation of China [21172149]
- Science Technology Department of Zhejiang Province [2012R10014-15]
Palladium-catalyzed Hiyama-type cross-coupling reactions of various arenesulfinates with organosilanes were achieved in good to excellent yields under aerobic conditions at 70 degrees C. Fluoride is essential, and tetrabutylammonium fluoride (TBAF) was shown to be the most efficient additive for these cross-coupling reactions. These cross-coupling reactions of the arenesulfinates provide high yields and show wide functional group tolerance, making them attractive alternative transformations to traditional cross-coupling approaches for carbon-carbon bond construction.
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