期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 2, 页码 803-808出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4023974
关键词
-
资金
- Natural Science Foundation of Inner Mongolia [2010KF02]
- Opening Project of Major Basic Research of Inner Mongolia [20130902]
An aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of a broad scope of tertiary amides under neutral and mild conditions. The mechanism may undergo the two key steps of oxidative addition of acyl C-O bond in parent ester and C-N bond cleavage of tertiary amine via an iminium-type intermediate.
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