期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 16, 页码 8176-8183出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4012199
关键词
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资金
- Chinese National Natural Science Foundation [21173178, 21232005]
- National Basic Research Program of China [2012CB821600]
- NFFTBS [J1210014]
- Program for Changjiang Scholars and Innovative Research Team in University
- Collaborative Innovation Center of Chemistry for Energy Materials
A new method for copper-catalyzed P-C bond formation through reaction of phosphorus nucleophiles with diaryliodonium salts at room temperature is described. Most target products are obtained with this method in high yields within a short reaction time of 10 min. It can be easily adapted to large-scale preparations. When unsymmetrical iodonium salts are employed, nucleophilic substitution occurs preferentially on the sterically hindered aromatic ring or the more electron-deficient ring.
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