期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 24, 页码 12837-12843出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4023233
关键词
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资金
- NIH [NIGMS R01 GM081376]
- Neuroscience Medicinal Chemistry Department of Janssen
Copper-mediated trifluoromethylation of unsaturated organotrifluoroborates with the Langlois reagent (NaSO2CF3) and TBHP allows the introduction of trifluoromethyl groups into a variety of organic substructures. The reactions are easy to set up, the conditions are mild and general, and the process provides access to trifluoromethylated alkynes, alkenes, arenes, and heteroarenes in fair to good yields.
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