期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 17, 页码 8909-8914出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo401498w
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资金
- NIH-NIGMS [GM-055382]
A one-pot anti-Markovnikov hydroamination of alkenes is reported. The synthesis of primary and secondary amines from unactivated olefins was accomplished in the presence of a variety of functional groups. Hydrozirconation, followed by amination with nitrogen electrophiles, provides exclusive anti-Markovnikov selectivity. Most products are isolated in high yields without the use of column chromatography.
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