期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 10, 页码 5007-5017出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo400888b
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Asahi Glass Foundation
- JSPS
- Grants-in-Aid for Scientific Research [24750089] Funding Source: KAKEN
A copper/N-heterocyclic carbene-catalyzed asymmetric allylic substitution of allyl phosphates with a silylboronate has been developed to give highly enantioenriched allylsilanes. High regioselectivity has been achieved by employing NaOH as the base, and this catalyst system is effective for both gamma-mono- and disubstituted allyl phosphates.
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