期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 21, 页码 11082-11086出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo401796g
关键词
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资金
- PRF-ACS
- NSF [CHE 1152996]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1152996] Funding Source: National Science Foundation
We explore in detail the iron-catalyzed benzylic fluorination of substrates containing aromatic rings and electron-withdrawing groups positioned beta to one another, thus providing direct access to beta-fluorinated adducts. This operationally convenient process can be thought of not only as a contribution to the timely problem of benzylic fluorination but also as a functional equivalent to a conjugate addition of fluoride, furnishing products in moderate to good yields and in excellent selectivity.
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