期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 7, 页码 3104-3112出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4000674
关键词
-
资金
- Shandong University
- National Science Foundation of China [21202093, 30925038]
A manganese dioxide (MnO2)-methanesulfonic acid (CH3SO3H) oxidation system has been developed to efficiently promote direct coupling of benzylic ethers and carbamates with simple ketones via oxidative C-H bond activation. The alkylation proceeds smoothly under air atmosphere to afford the corresponding products in good to excellent yields (53-87%). The employment of the combination of MnO2 and CH3SO3H is attractive on the basis of economical and environmental issues.
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