期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 2, 页码 814-817出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo402457x
关键词
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资金
- Alexander von Humboldt Foundation
Light-induced Brook rearrangements of acylsilanes facilitate silylacylation reactions of electron-deficient internal alkynes. A wide range of aromatic substituents on the acylsilane aryl group are tolerated, affording a series of functionalized enonyl silanes. The presence of electron-withdrawing substituents on the alkyne is crucial for the success of the addition process.
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