期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 23, 页码 12182-12188出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4015547
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资金
- Council of Scientific and Industrial Research (CSIR), New Delhi [01(2332)/09/EMR-II]
Trimethylsilyl trifluoromethanesulfonate (TMSOTf) can be efficiently used for Prins cyclization of acrylyl enol ethers to 5,6-dihydro-2H-pyran-2-acetates stereo- and regioselectively in good yields. The methodology was used for the total synthesis of natural product (+)-civet.
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