期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 11, 页码 5705-5710出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4003773
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-
资金
- Ontario Ministry of Research and Innovation
The reaction of 3-halo-4-aminopyridines with acyl chlorides and triethylamine is described. The pyridin-4-y1 alpha-substituted acetamide products were obtained in moderate to high yields. The presented rearrangement reaction, in which the presumed N-acylated intermediate reacts intramolecularly via nucleophilic aromatic substitution, results in a formal two-carbon insertion.
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