期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 7, 页码 3400-3404出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo400071h
关键词
-
资金
- Ministry of Science and Technology [2009ZX09501-00]
- Chinese Academy of Sciences
- National Natural Science Foundation of China [20632050, 20921091]
CuBr-catalyzed coupling reaction of 2-halobenzonitriles with hydrazine carboxylic esters and CuBr/4-hydroxy-L-proline-catalyzed coupling reaction of 2-bromobenzonitriles with N'-arylbenzohydrazides proceed smoothly at 60-90 degrees C to provide substituted 3-aminoindazoles through a cascade coupling/condensation (or coupling/deacylation/condensation) process. A wide range of 3-aminoindazoles with substituents at both the 1-position and the phenyl ring part can be prepared from the corresponding coupling partners.
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