4.7 Article

Palladium-Catalyzed Methylation of Alkynyl C(sp)-H Bonds with Dimethyl Sulfonium Ylides

期刊

JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 20, 页码 10421-10426

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jo401851m

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资金

  1. National Natural Science Foundation of China [21172060]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20120161110041]
  3. Hunan Provincial Natural Science Foundation of China [13JJ2018]
  4. Hunan Provincial Innovation Foundation for Postgraduate [CX2010B219]

向作者/读者索取更多资源

A novel palladium-catalyzed methylation protocol for the synthesis of methyl-functionalized internal alkynes has been established. This methylation method is achieved through a C(sp)-C(sp(3)) bond formation process and represents a new synthetic application of sulfonium ylides.

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