期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 12, 页码 6332-6337出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4010734
关键词
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资金
- MEXT [20102014]
- Kansai University
The Pd-catalyzed oxidative amination of olefins with primary anilines has been achieved using molecular dioxygen as the sole oxidant. The use of ortho-substituted primary anilines such as ortho-toluidine was the key to the successful development of this reaction, providing the corresponding N-alkenyl substituted anilines in high yields with unusually high levels of Z-selectivity.
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