期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 15, 页码 7601-7616出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4011798
关键词
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资金
- USDA [2911-10006-30362]
- International Collaboration Program
- Perm Krai Governor and Department of Education (Russia)
- NSF
- SMART Fellowship
- US Navy Undergraduate Fellowship
- NSF REU Award
- KU UGRA program
- Department of Chemistry, University of Kansas
- NSF-MRI [CHE-0923449]
A highly chemo- and diastereoselective protocol toward amino-substituted donor acceptor cyclopropanes via the formal nucleophilic displacement in bromocyclopropanes is described. A wide range of N-nucleophiles, including carboxamides, sulfonamides, azoles, and anilines, can be efficiently employed in this transformation, providing expeditious access to stereochemically defined and densely functionalized cydopropylamine derivatives.
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