期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 7, 页码 3341-3347出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo300126n
关键词
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资金
- National Natural Science Foundation of China [91021004]
- National Basic Research Program of China [2011CB921402]
The palladium-catalyzed ortho-arylation of benzamides by aryl iodides has been demonstrated with the simplest amide CONH2 as a directing group for the first time. This protocol can be applied to various benzamides and aryl iodides with both electron-donating and electron-withdrawing groups. In addition, the synthesized biphenyl-2-carboxamides can be further transformed to other biphenyl derivatives such as nitriles, carboxylic acids, carbamates, and amines.
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