期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 8, 页码 4143-4147出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo3002535
关键词
-
资金
- National Natural Foundation of China
- Ministry of Science and Technology [2011CB808600]
- Chinese Academy of Sciences
A Me-DuPhos-catalyzed efficient asymmetric [3 + 2] cycloaddition reaction between Morita-Baylis-Hillman carbonates of isatins and N-phenylmaleimide has been developed. This reaction constructs three chiral centers in one step to afford spirocyclopentaneoxindoles in good yields (up to 84%) with excellent diastereo- and enantioselectivies (up to 99% ee).
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