期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 17, 页码 7157-7165出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo301117b
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资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- National Natural Science Foundation of China [21072142]
- Jiangsu Province NSF [BK2011408]
- Jiangsu Province Department of Education [10KJB150002]
A metal-free oxidative coupling of methyl ketones and primary or secondary amines to alpha-ketoamides has been developed. Four intermediates, alpha-iodoketone, alpha-aminoketone, iminium intermediate, and alpha-hydroxy amine have been identified through a series of control experiments. The atom-economic methodology can be scaled-up, tolerates a variety of functional groups, and is operationally simple.
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