期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 24, 页码 11393-11398出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo302322w
关键词
-
资金
- Swedish Research Council
- Knut and Alice Wallenberg Foundation
A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the Mo(CO)(6)-mediated and palladium(0)-catalyzed conversion to benzamides, while the identical one-vessel protocol afforded extensive reduction of the nitro functionality. The above-mentioned bridged two-compartment protocol furnished good results with both primary amines and secondary amines and sluggish aniline nucleophiles at 65-85 degrees C reaction temperatures.
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