期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 6, 页码 2986-2991出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo3000223
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资金
- Ministerio de Ciencia e Innovacion [CTQ2009-07733]
- Universidad del Pais Vasco [UFI11/22]
The Parham cyclization-intermolecular alpha-amidoalkylation sequence results in the facile enantioselective synthesis of 12b-substituted isoindoloisoquinolines (ee up to 95%) using BINOL-derived Bronsted acids. alpha-Amidoalkylation of indole occurs through :he formation of a chiral conjugate base/bicyclic quaternary N-acyliminium ion pair.
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