期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 11, 页码 5179-5183出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo300692d
关键词
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资金
- National Natural Science Foundation of China [20932002]
- National Basic Research Program of China (973 Program) [2011CB808600]
- Guangdong Natural Science Foundation [10351064101000000]
- China Postdoctoral Science Foundation [2011M501318]
- Fundamental Research Funds for the Central Universities [2012ZB0011]
A regioselective synthesis of 2,5-disubstituted furans using copper(I) catalyst from haloalkynes in a one-pot procedure has been reported. This chemistry proceeds through the hydration reaction of 1,3-diynes, which can be readily prepared from the coupling reaction of haloalkynes in the presence of CuI. The procedure also can be used for the facile synthesis of 2,5-disubstituted thiophenes.
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