期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 13, 页码 5624-5632出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo300800b
关键词
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资金
- startup funds from Wayne State University
- Schaap Faculty Scholar Award
- CAREER Award from the National Science Foundation [CHE-0955000]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0955000] Funding Source: National Science Foundation
The development of efficient methods for the asymmetric Mukaiyama aldol reaction in aqueous solution has received great attention. We have developed a new series of chiral lanthanide-containing complexes that produce Mukaiyama aldol products with outstanding enantioselectivities. In this paper, we describe an optimized ligand synthesis, trends in stereoselectivity that result from changing lanthanide ions, and an exploration of substrate scope that includes aromatic and aliphatic aldehydes and silyl enol ethers derived from aromatic and aliphatic ketones.
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