期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 5, 页码 2543-2547出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo202537e
关键词
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资金
- National Institutes of Health [GM58160]
- MIT
- Japan Society for the Promotion of Sciences (JSPS)
- Bristol-Myers Squibb
A new biarylphosphine ligand, Me-3(OMe)tBuXPhos (L3), was designed as a surrogate for Me(4)tBuXPhos (L1). The Me-3(OMe)tBuXPhos could be prepared in a chromatography-free manner from inexpensive and readily available 2,3,6-trimethylphenol. Comparative studies demonstrated that a catalyst based on Me-3(OMe)tBuXPhos displayed the same reactivity as a catalyst based on Me(4)tBuXPhos for Pd-catalyzed C-N and C-O bond-forming processes.
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