期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 11, 页码 5056-5062出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo3005149
关键词
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资金
- Ministere de l'Enseignement Superieur et de la Recherche
- Spanish MICINN [CTQ2011-23336]
A new protocol for the direct cobalt-catalyzed vinylation of aryl halides using beta-halostyrene has been developed in order to form functionalized stilbenes. A variety of aromatic halides featuring different reactive group were employed. This method proceeded smoothly with a total retention of the double bond configuration in the presence of triphenylphosphine as ligand. Preliminary DFT calculations rationnalize these results and proposed a reaction pathway in agreement with the experimental conditions. This procedure offers a new route to the stereoselective synthesis of stilbenes.
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