期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 7, 页码 3557-3562出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo202628c
关键词
-
资金
- 973 projects [2011CB512005]
- Key Laboratory for the Chemistry and Moecular Engineering of Medicinal Resources (Guangxi Normal University)
- Ministry of Education of China [CMEMR2011-15]
- Guangxi Natural Science Foundation of China [2011GXNSFD018010, 2010GXNSFF013001]
A novel and efficient procedure for the synthesis of delta,gamma-alkynyl esters by the conjugate addition of alkynylsilanes to acrylate esters in the presence of a catalytic amount of indium(III) chloride has been developed. This method provides a rapid and efficient access to substituted delta,gamma-alkynyl esters.
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