期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 5, 页码 2254-2262出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo2024784
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资金
- National Science Council (NSC)
- MOE ATU of the Ministry of Education, Taiwan, the Republic of China
An efficient synthetic pathway for the synthesis of biscalix[4]arenes 5-10 using 1,3-dipolar cycloaddition reactions is reported. Biscalix[4]arene 10 is capable of forming a complex with methyl viologen because of favorable cation-pi interactions and a proper cavity size to accommodate the guest. Moreover, biscalix[4]arenes 8a and 8b were found to be atropisomers at room temperature. These two conformers were unable to exchange at room temperature because of the restricted rotation of the C-9-C-11 or C-10-C-12 bonds of the beta-amino-alpha,beta-unsaturated ketones of anthracene.
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