期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 3, 页码 1422-1434出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo2022668
关键词
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资金
- National Basic Research Program (973 Program) of China [2010CB833203]
- National Natural Science Foundation of China [20972060, 21061160494]
- Specialized Research Fund for the Doctoral Program of Higher Education [20090211110007]
- 111 Project
Monoaryne and monoisobenzofuran analogues of a C-3v-symmetrical tribenzotriquinacene (TBTQ) were generated in situ and trapped with various dienes and dienophiles, respectively. In this way, a series of single-wing extended TBTQ derivatives bearing the bowl-shaped TBTQ unit in different topographical expositions have become accessible. This includes some novel tribenzotriquinacene dimers, in which two TBTQ bowls are attached in syn- or anti-orientation at the terminal positions of rigid linker units. Several of these compounds have been characterized by both spectroscopy and X-ray structural analysis. The efficient access to the TBTQ dimers studies of novel container compounds and supramolecular architectures.
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