期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 7, 页码 3318-3324出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo300129m
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [22550044]
- Chuo University
- Grants-in-Aid for Scientific Research [22550044] Funding Source: KAKEN
Newly developed ClickFerrophos II ligands were applied in the hydrogenation of alpha,beta-unsaturated phosphonates. The use of a rhodium/ClickFerrophos II catalyst was examined in the hydrogenation of fimctionalized alpha,beta-unsaturated phosphonates and was revealed to be effective for beta-alkyl-beta-aryl or beta-dialkyl phosphonates, (Z)-beta-enolester phosphonates, and alpha-phenylethenyl phosphonates, producing the corresponding chiral phosphonates in good yields with high enantioselectivities (up to 96% ee).
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