期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 7, 页码 3609-3614出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo300039q
关键词
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资金
- State Key Laboratory of Phytochemistry and Plant Resources in West China
- National Science and Technology Major Project titled the Development of Key Technology for the Combinatorial Synthesis of Privileged Scaffolds [2009ZX09501-012]
- National Basic Research Program of China (973 Program) [2010CB833201]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, the Ministry of Education of China
- Shenzhen Basic Research Program [JC200903160352A]
A concise synthetic pathway that enables the stereoselective construction of the tetracyclic core of nanolobatolide has been developed by applying a tandem ring-closing metathesis (RCM) reaction of dienynes, a Eu(fod)(3)-catalyzed intermolecular Diels-Alder reaction, and a biomimetic epoxide opening reaction as key steps.
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