期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 17, 页码 7392-7400出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo3011683
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资金
- National Science Foundation [DMR-1055705]
- American Chemical Society Petroleum Research Fund
- Office of Energy Efficiency and Renewable Energy of the U.S. Department of Energy [DE-AC36-08GO28308]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1055705] Funding Source: National Science Foundation
- Div Of Industrial Innovation & Partnersh
- Directorate For Engineering [1034710] Funding Source: National Science Foundation
- Div Of Industrial Innovation & Partnersh
- Directorate For Engineering [1034720] Funding Source: National Science Foundation
A series of dialdehyde compounds were synthesized and reacted with the complementary triamines (either planar or pyramidal with a 109.5 degrees vertex) in a 3:2 ratio to explore the structural requirements on the building blocks for the successful construction of shape-persistent, covalent organic polyhedrons (COPs). Structural variations in the building blocks included the distance and angle between the two reactive sites (aldehyde or amine functional groups) and the absence/presence of solubilizing chains. Computer modeling was utilized to determine and compare the thermodynamic stabilities of some of these COP structures. Furthermore, gas adsorption studies were performed to explore the potential of these molecular cages for gas separation, particularly carbon capture, applications.
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